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Titolo:
DEGREE OF MISCIBILITY BETWEEN NONISOMORPHOUS PLASTIC PHASES - BINARY-SYSTEM NPG (NEOPENTYL GLYCOL)-TRIS [TRIS(HYDROXYMETHYL)AMINOMETHANE]
Autore:
BARRIO M; LOPEZ DO; TAMARIT JL; NEGRIER P; HAGET Y;
Indirizzi:
UNIV POLITECN CATALUNYA,DEPT FIS & ENGN NUCL,DIAGONAL 647 E-08028 BARCELONA SPAIN UNIV BORDEAUX 1,CNRS,CRISTALLOG & PHYS CRISTALLINE LAB F-33405 TALENCE FRANCE
Titolo Testata:
Journal of materials chemistry
fascicolo: 3, volume: 5, anno: 1995,
pagine: 431 - 439
SICI:
0959-9428(1995)5:3<431:DOMBNP>2.0.ZU;2-G
Fonte:
ISI
Lingua:
ENG
Soggetto:
DIELECTRIC-RELAXATION; NEUTRON-SCATTERING; ALICYCLIC ALCOHOLS; MOLECULAR-MOTION; THERMAL-ANALYSIS; CRYSTALS; PRESSURE; LIQUID; 2-METHYL-2-NITROPROPANE; REORIENTATIONS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
52
Recensione:
Indirizzi per estratti:
Citazione:
M. Barrio et al., "DEGREE OF MISCIBILITY BETWEEN NONISOMORPHOUS PLASTIC PHASES - BINARY-SYSTEM NPG (NEOPENTYL GLYCOL)-TRIS [TRIS(HYDROXYMETHYL)AMINOMETHANE]", Journal of materials chemistry, 5(3), 1995, pp. 431-439

Abstract

The experimental phase diagram between the plastic crystals neopentylglycol (NPG) and tris(hydroxymethyl)amino-methane (TRIS) has been established. The importance of the use of complementary techniques with different timescales in order to obtain the mast realistic phase diagram is underlined. The miscibility is discussed on the basis of the geometric conditions (size and shape of molecules and unit-cell dimensions) and of the role of the intermolecular interactions in the structure of the mixed crystals. Binary phase diagrams formed by related, previously reported neopentane derivatives are also analysed in the same manner.

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Documento generato il 21/09/20 alle ore 06:30:13