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Titolo:
SYNTHESIS AND CHARACTERIZATION OF THE TET RAHEDRANES [CPM(CO)(2)](3)P(M=MO, W) AND THEIR DERIVATIVES [CPMO(CO)(2)](3)P-MO(CO)(5) AND [CPW(CO)(2)](3)P-W(CO)(5)
Autore:
KILTHAU T; NUBER B; ZIEGLER ML;
Indirizzi:
UNIV HEIDELBERG,INST ANORGAN CHEM,NEUENHEIMER FELD 270 D-69120 HEIDELBERG GERMANY
Titolo Testata:
Chemische Berichte
fascicolo: 2, volume: 128, anno: 1995,
pagine: 197 - 199
SICI:
0009-2940(1995)128:2<197:SACOTT>2.0.ZU;2-4
Fonte:
ISI
Lingua:
GER
Soggetto:
COMPLEX;
Keywords:
MU(3)-PHOSPHORUS-TRIMOLYBDENUM TETRAHEDRANE; MU(3)-PHOSPHORUS-TRITUNGSTEN TETRAHEDRANE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
9
Recensione:
Indirizzi per estratti:
Citazione:
T. Kilthau et al., "SYNTHESIS AND CHARACTERIZATION OF THE TET RAHEDRANES [CPM(CO)(2)](3)P(M=MO, W) AND THEIR DERIVATIVES [CPMO(CO)(2)](3)P-MO(CO)(5) AND [CPW(CO)(2)](3)P-W(CO)(5)", Chemische Berichte, 128(2), 1995, pp. 197-199

Abstract

The reaction of Na[CpM(CO)(3)] (M = Mo, W) with PCl3 in diglyme yields the cluster compounds [CpMo(CO)(2)]P-3-Mo(CO)(5) (2a) and [CpW(CO)(2)]P-3-W(CO)(5) (2b) in good yields as well as the tetrahedranes [CpMo(CO)(2)]P-3 (3a) and[CpW(CO)(2)]P-3 (3b) as side products. Compounds 3a, b are obtained independently by the reaction of 2a, b with PPh(3). The clusters 2a, b and 3a, b were characterized spectroscopically (IR, NMR, MS), and X-ray structure determinations were carried out on 2a, b.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/11/20 alle ore 00:48:58