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Titolo:
SULFOXIDES OF HIGH ENANTIOPURITY FROM BACTERIAL DIOXYGENASE-CATALYZEDOXIDATION
Autore:
ALLEN CCR; BOYD DR; DALTON H; SHARMA ND; HAUGHEY SA; MCMORDIE RAS; MCMURRAY BT; SHELDRAKE GN; SPROULE K;
Indirizzi:
QUEENS UNIV BELFAST,SCH CHEM BELFAST BT9 5AG ANTRIM NORTH IRELAND QUEENS UNIV BELFAST,SCH CHEM BELFAST BT9 5AG ANTRIM NORTH IRELAND UNIV WARWICK,DEPT BIOL SCI COVENTRY CV4 7AL W MIDLANDS ENGLAND ZENECA SPECIAL MANCHESTER M9 3DA LANCS ENGLAND
Titolo Testata:
Journal of the Chemical Society, Chemical Communications
fascicolo: 2, , anno: 1995,
pagine: 119 - 120
SICI:
0022-4936(1995):2<119:SOHEFB>2.0.ZU;2-6
Fonte:
ISI
Lingua:
ENG
Soggetto:
ENZYMATIC OXIDATION; MICROBIAL OXIDATION; CYCLOHEXANONE MONOOXYGENASE; ORGANIC SULFIDES; OXYGENATION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
18
Recensione:
Indirizzi per estratti:
Citazione:
C.C.R. Allen et al., "SULFOXIDES OF HIGH ENANTIOPURITY FROM BACTERIAL DIOXYGENASE-CATALYZEDOXIDATION", Journal of the Chemical Society, Chemical Communications, (2), 1995, pp. 119-120

Abstract

Selected strains of the bacterium Pseudomonas putida (previously shown to effect dioxygenase-catalysed asymmetric cis-dihydroxylation of alkenes) have been found to yield chiral sulfoxides from the corresponding sulfides with a strong preference for the (R)- or (S)-configurations but without evidence of sulfone formation; similar results obtained using an Escherichia coli clone (pKST11, containing the Tod C1 C2 B and A genes encoding toluene dioxygenase from P. putida NCIMB 11767) areagain consistent with a stereoselective dioxygenase-catalysed sulfoxidation.

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Documento generato il 25/11/20 alle ore 07:17:48