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Titolo:
REACTION OF URANIUM TETRACHLORIDE WITH TRIMETHYLSILYLCYCLOPENTADIENE - CRYSTAL-STRUCTURE OF A DICHLOROMETHANE ADDUCT OF MU-CL))(3)(MU(3)-CL)(2)][(U(CP)CL-2)(2)(MU-CL)(3)] (CP=ETA-C5H5)
Autore:
ARLIGUIE T; EPHRITIKHINE M; LANCE M; VIGNER J; NIERLICH M;
Indirizzi:
CTR ETUD SACLAY,CEA,CHIM URANIUM LAB,SERV CHIM MOLEC,CNRS,URA 331 F-91191 GIF SUR YVETTE FRANCE CTR ETUD SACLAY,CEA,CHIM URANIUM LAB,SERV CHIM MOLEC,CNRS,URA 331 F-91191 GIF SUR YVETTE FRANCE CTR ETUD SACLAY,CEA,CRISTALLOG LAB,SERV CHIM MOLEC,CNRS,URA 331 F-91191 GIF SUR YVETTE FRANCE
Titolo Testata:
Journal of organometallic chemistry
fascicolo: 1-2, volume: 484, anno: 1994,
pagine: 195 - 201
SICI:
0022-328X(1994)484:1-2<195:ROUTWT>2.0.ZU;2-I
Fonte:
ISI
Lingua:
ENG
Soggetto:
LIGAND-EXCHANGE REACTIONS; TRIPHENYLPHOSPHINE OXIDE; COMPLEXES; TETRAHYDROFURAN; TRICHLORIDE; DERIVATIVES; DICHLORIDE; ZIRCONIUM; CHLORIDES; HALIDES;
Keywords:
URANIUM; CYCLOPENTADIENYL; X-RAY STRUCTURE; BIS(CYCLOPENTADIENYL)URANIUM; ACTINIDE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
29
Recensione:
Indirizzi per estratti:
Citazione:
T. Arliguie et al., "REACTION OF URANIUM TETRACHLORIDE WITH TRIMETHYLSILYLCYCLOPENTADIENE - CRYSTAL-STRUCTURE OF A DICHLOROMETHANE ADDUCT OF MU-CL))(3)(MU(3)-CL)(2)][(U(CP)CL-2)(2)(MU-CL)(3)] (CP=ETA-C5H5)", Journal of organometallic chemistry, 484(1-2), 1994, pp. 195-201

Abstract

The uranium tetrachloride reacts in dichloromethane with 1 and 3 equivalents of trimethylsilylcyclopentadiene to give [U(cp)Cl-3] (1) and [U(cp)(3)Cl] (3) respectively (cp = eta-C5H5). The title compound 2 wasisolated from the reaction of UCl4 with 2 equivalents of the silylated cyclopentadiene. Complex 2 is in equilibrium with 1 and 3 in refluxing dichloromethane.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 21/09/20 alle ore 06:23:36