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Titolo:
SYNTHESIS AND CHARACTERIZATION OF PLATINUM(0) COMPLEXES OF PROPENOATES - X-RAY-DIFFRACTION STUDY OF [PT(CH2=CHCO(2)CH(2)PH)(PPH(3))(2)]
Autore:
CHALONER PA; DAVIES SE; HITCHCOCK PB;
Indirizzi:
UNIV SUSSEX,SCH CHEM & MOL SCI BRIGHTON BN1 9QJ E SUSSEX ENGLAND
Titolo Testata:
Journal of organometallic chemistry
fascicolo: 1-2, volume: 527, anno: 1997,
pagine: 145 - 154
SICI:
0022-328X(1997)527:1-2<145:SACOPC>2.0.ZU;2-S
Fonte:
ISI
Lingua:
ENG
Soggetto:
CHIRAL DERIVATIZING AGENTS; ORGANOMETALLIC CHEMISTRY; POLYSUBSTITUTED OLEFINS; ENANTIOMERIC PURITY; NMR-SPECTRA; LIGANDS; P-31; REARRANGEMENT; CATALYSIS;
Keywords:
PLATINUM; ALKENE; X-RAY DIFFRACTION; NUCLEAR MAGNETIC RESONANCE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
48
Recensione:
Indirizzi per estratti:
Citazione:
P.A. Chaloner et al., "SYNTHESIS AND CHARACTERIZATION OF PLATINUM(0) COMPLEXES OF PROPENOATES - X-RAY-DIFFRACTION STUDY OF [PT(CH2=CHCO(2)CH(2)PH)(PPH(3))(2)]", Journal of organometallic chemistry, 527(1-2), 1997, pp. 145-154

Abstract

Reaction of [Pt(C2H4)(PPh(3))(2)] with propenoate or 2-methylpropenoate esters gave the complexes [Pt(propenoate)(PPh(3))(2)] in good yield. These have been characterised by H-1, C-13, P-31 and Pt-195 NMR spectroscopy. The complex of benzyl propenoate has been characterised in adiffraction study. Reaction of the complexes produced with tricyclohexylphosphine, PCy(3), gave [Pt(propenoate)(PCy(3))(PPh(3))]. The propenoate complexes were shown to be more stable than those of the 2-methylpropenoates.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 25/11/20 alle ore 09:17:47