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Titolo:
SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURE OF [(CH3)(2)C(C5H4)(2)]FE-2(MU-CO)(2)(CO)(2)
Autore:
VANDENBERG W; CROMSIGT JAMTC; BOSMAN WP; SMITS JMM; DEGELDER R; GAL AW; HECK J;
Indirizzi:
UNIV HAMBURG,INST ANORGAN & ANGEW CHEM,MARTIN LUTHER KING PL 6 D-20146 HAMBURG GERMANY UNIV HAMBURG,INST ANORGAN & ANGEW CHEM D-20146 HAMBURG GERMANY CATHOLIC UNIV NIJMEGEN,NIJMEGEN SON RES CTR,DEPT INORGAN CHEM NL-6525ED NIJMEGEN NETHERLANDS
Titolo Testata:
Journal of organometallic chemistry
fascicolo: 1-2, volume: 524, anno: 1996,
pagine: 281 - 284
SICI:
0022-328X(1996)524:1-2<281:SCAMO[>2.0.ZU;2-P
Fonte:
ISI
Lingua:
ENG
Soggetto:
COMPLEXES; CHEMISTRY; CRYSTAL;
Keywords:
CARBON MONOXIDE; CYCLOPENTADIENYL; IRON; NUCLEAR MAGNETIC RESONANCE; X-RAY DIFFRACTION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
20
Recensione:
Indirizzi per estratti:
Citazione:
W. Vandenberg et al., "SYNTHESIS, CHARACTERIZATION, AND MOLECULAR-STRUCTURE OF [(CH3)(2)C(C5H4)(2)]FE-2(MU-CO)(2)(CO)(2)", Journal of organometallic chemistry, 524(1-2), 1996, pp. 281-284

Abstract

[(CH3)(2)C(C5H4)(2)]Fe-2(mu-CO)(2)(CO)(2) (1) has been synthesized from 2,2-dicyclopentadienyl propane and pentacarbonyliron in 26% yield. The crystal and molecular structure of 1 has been determined by X-ray diffraction. The molecule has the expected carbonyl-bridged structure with a cis configuration of the cyclopentadienyl rings. The Fe-Fe distance of 2.484 Angstrom is the shortest one reported to date for ring-bridged dicyclopentadienyl di-iron tetracarbonyl complexes.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 27/11/20 alle ore 10:38:26