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Titolo:
CATECHOLALANE (1,3,2-BENZODIOXALUMINOLE) AS A SELECTIVE REDUCING AGENT
Autore:
CHA JS; CHANG SW; LEE JE; KIM JM; KWON OO; LEE HS; SONG HC;
Indirizzi:
YEUNGNAM UNIV,DEPT CHEM KYONGSAN SOUTH KOREA TAEGU HYOSUNG CATHOLIC UNIV,DEPT CHEM EDUC KYONGSAN 713900 SOUTH KOREA KYUNGPOOK NATL UNIV,DEPT DYEING & FINISHING TAEGU 702701 SOUTH KOREA
Titolo Testata:
Bulletin of the Korean Chemical Society
fascicolo: 8, volume: 17, anno: 1996,
pagine: 720 - 724
SICI:
0253-2964(1996)17:8<720:C(AASR>2.0.ZU;2-N
Fonte:
ISI
Lingua:
ENG
Soggetto:
REPRESENTATIVE FUNCTIONAL-GROUPS; ORGANIC-COMPOUNDS; CATECHOLBORANE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
11
Recensione:
Indirizzi per estratti:
Citazione:
J.S. Cha et al., "CATECHOLALANE (1,3,2-BENZODIOXALUMINOLE) AS A SELECTIVE REDUCING AGENT", Bulletin of the Korean Chemical Society, 17(8), 1996, pp. 720-724

Abstract

Catecholalane (1,3,2-Benzodioxaluminole, CA) prepared from catechol and aluminum hydride in tetrahydrofuran (THF) is found to be a selective reducing agent, The systematic study in order to characterize the reducing properties of the reagent under practical conditions (THF, 0 or25 degrees C, the quantitative amount of reagent to compound) has been done. The reagent reduces aldehydes, ketones, esters and acid chlorides to the corresponding alcohols, and primary amides to the corresponding amines. Especially noteworthy is that the reagent can convert both aromatic and aliphatic nitriles to the corresponding aldehydes in very high yields.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 14/08/20 alle ore 07:44:38