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Titolo:
-TETRAAZACYCLOTETRADECANE-N,N',N'',N''')COPPER(II) DIPERCHLORATE
Autore:
TAHIROV TH; LU TH; LIAO FL; WANG SL; CHEN BH; CHI TY; CHUNG CS;
Indirizzi:
NATL TSING HUA UNIV,DEPT PHYS HSINCHU 300 TAIWAN NATL TSING HUA UNIV,DEPT CHEM HSINCHU 300 TAIWAN
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 52, anno: 1996,
parte:, 11
pagine: 2687 - 2689
SICI:
0108-2701(1996)52:<2687:-D>2.0.ZU;2-H
Fonte:
ISI
Lingua:
ENG
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
6
Recensione:
Indirizzi per estratti:
Citazione:
T.H. Tahirov et al., "-TETRAAZACYCLOTETRADECANE-N,N',N'',N''')COPPER(II) DIPERCHLORATE", Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2687-2689

Abstract

The Cu-II ion in the title compound, [Cu(C14H32N4)-(H2O)](ClO4)(2), is five-coordinate in a distorted square pyramidal geometry, with the four N atoms of the macrocyclic ligand equatorial and the O atom of theaqua group axial. The tetradentate ligand adopts its most stable conformation with the two six-membered rings in chair conformations and the two five-membered rings in gauche conformations. The complex has a 1SR,4SR,8SR,11SR configuration for the four chiral N-atom centers and a5RS,12RS configuration for the two chiral C-atom centers.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 11/08/20 alle ore 14:04:29