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Titolo:
DIENE-N,N',N'',N''')DI(ISOTHIOCYANATO-N)COBALT(II) THIOCYANATE
Autore:
LU TH; TAHIROV TH; CHEN BH; LAI CY; CHUNG CS;
Indirizzi:
NATL TSING HUA UNIV,DEPT PHYS HSINCHU 30043 TAIWAN NATL TSING HUA UNIV,DEPT CHEM HSINCHU 30043 TAIWAN
Titolo Testata:
Acta crystallographica. Section C, Crystal structure communications
, volume: 52, anno: 1996,
parte:, 11
pagine: 2684 - 2687
SICI:
0108-2701(1996)52:<2684:DT>2.0.ZU;2-W
Fonte:
ISI
Lingua:
ENG
Soggetto:
PERCHLORATE; CHLORIDE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
14
Recensione:
Indirizzi per estratti:
Citazione:
T.H. Lu et al., "DIENE-N,N',N'',N''')DI(ISOTHIOCYANATO-N)COBALT(II) THIOCYANATE", Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 2684-2687

Abstract

The Co-III ion in the title compound, [CO(NCS)(2)(C16H32-N-4)](SCN), is six-coordinate in a distorted octahedral environment, with the fourN atoms of the macrocyclic tetradentate ligand equatorial and the N atoms of two isothiocyanato groups axial. The tetradentate macrocyclic ligand is in a planar conformation, with the two five-membered rings in gauche conformations and the two six-membered rings in twist conformations. The complex has an RR or SS configuration for the two chiral amine N centres. Intermolecular hydrogen bonds between the two NH groups and the unbonded thiocyanate anion help stabilize the crystal structure.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 10/07/20 alle ore 02:57:53