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Titolo:
SOLID-LIQUID EQUILIBRIA FOR SYSTEMS CONTAINING LONG-CHAIN 1-ALKANOLS .1. EXPERIMENTAL-DATA FOR 1-DODECANOL, 1-TETRADECANOL, 1-HEXADECANOL, 2-OCTADECANOL OR 1-ICOSANOL-BENZENE OR 1-ICOSANOL-TOLUENE MIXTURES - CHARACTERIZATION IN TERMS OF DISQUAC
Autore:
DOMANSKA U; GONZALEZ JA;
Indirizzi:
UNIV VALLADOLID,DEPT FIS APLICADA 2 E-47071 VALLADOLID SPAIN UNIV VALLADOLID,DEPT FIS APLICADA 2 E-47071 VALLADOLID SPAIN WARSAW UNIV TECHNOL,DEPT CHEM,DIV PHYS CHEM PL-00664 WARSAW POLAND
Titolo Testata:
Fluid phase equilibria
fascicolo: 1-2, volume: 119, anno: 1996,
pagine: 131 - 151
SICI:
0378-3812(1996)119:1-2<131:SEFSCL>2.0.ZU;2-L
Fonte:
ISI
Lingua:
ENG
Soggetto:
GROUP CONTRIBUTION MODEL; MOLECULAR ADDITION-COMPOUNDS; PHASE-EQUILIBRIA; ORGANIC MIXTURES; EXCESS FUNCTIONS; TERNARY-SYSTEMS; ENTHALPIES; PREDICTION; SOLUBILITY; TETRACHLOROMETHANE;
Keywords:
EXPERIMENTAL; SOLID-LIQUID EQUILIBRIA; 1-ALKANOLS; TRANSITIONS; GROUP CONTRIBUTIONS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
55
Recensione:
Indirizzi per estratti:
Citazione:
U. Domanska e J.A. Gonzalez, "SOLID-LIQUID EQUILIBRIA FOR SYSTEMS CONTAINING LONG-CHAIN 1-ALKANOLS .1. EXPERIMENTAL-DATA FOR 1-DODECANOL, 1-TETRADECANOL, 1-HEXADECANOL, 2-OCTADECANOL OR 1-ICOSANOL-BENZENE OR 1-ICOSANOL-TOLUENE MIXTURES - CHARACTERIZATION IN TERMS OF DISQUAC", Fluid phase equilibria, 119(1-2), 1996, pp. 131-151

Abstract

Solid-liquid equilibrium temperatures for binary mixtures of long-chain 1-alkanols (1-dodecanol, 1-tetradecanol, 1-hexadecanol, 1-octadecanol and 1-icosanol) and benzene or toluene have been measured by a dynamic method between 276 K and the melting point of the alcohol. These data are used, taking into consideration the two solid-solid first-order transitions observed in the 1-alkanols, to characterize in terms of DISQUAC the hydroxyl-aromatic interactions present in the investigatedmixtures. The relative standard deviations for the equilibrium temperatures are less than 0.01 for most of the systems.

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Documento generato il 26/09/20 alle ore 04:07:52