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Titolo:
DINUCLEAR RHODIUM-RHODIUM AND RHODIUM-PALLADIUM COMPLEXES WITH DIFFERENT BRIDGING LIGANDS - CRYSTAL-STRUCTURE OF [RH-2(MU-SPPH(2))(MU-CL)(COD)(2)]
Autore:
PINILLOS MT; JARAUTA MP; ELDUQUE A; LAHOZ FJ; ORO LA;
Indirizzi:
UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN E-50009 ZARAGOZA SPAIN UNIV ZARAGOZA,CSIC,INST CIENCIA MAT ARAGON,DEPT QUIM INORGAN E-50009 ZARAGOZA SPAIN
Titolo Testata:
Journal of organometallic chemistry
fascicolo: 1-2, volume: 514, anno: 1996,
pagine: 119 - 124
SICI:
0022-328X(1996)514:1-2<119:DRARCW>2.0.ZU;2-O
Fonte:
ISI
Lingua:
ENG
Soggetto:
SECONDARY PHOSPHINE CHALCOGENIDES; MOLECULAR-STRUCTURE; PLATINUM COMPLEXES; METAL-COMPLEXES; HETEROCYCLES; BINUCLEAR; SULFIDES; CLEAVAGE; BOND; PD;
Keywords:
RH; PD; SULFIDES; DINUCLEAR COMPLEXES; THIOPHOSPHINITO; X-RAY STRUCTURES; HETERONUCLEAR COMPLEXES;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
37
Recensione:
Indirizzi per estratti:
Citazione:
M.T. Pinillos et al., "DINUCLEAR RHODIUM-RHODIUM AND RHODIUM-PALLADIUM COMPLEXES WITH DIFFERENT BRIDGING LIGANDS - CRYSTAL-STRUCTURE OF [RH-2(MU-SPPH(2))(MU-CL)(COD)(2)]", Journal of organometallic chemistry, 514(1-2), 1996, pp. 119-124

Abstract

Homo- and hetero-dinuclear complexes of general formulae [Rh-2(mu-SPPh(2))(mu-Cl)(diolefin)(2)] (diolefin = 1,5-cyclooctadiene (COD) (1), tetrafluorobenzobarrelene (TFB) (2)) and [RhPd(mu-SPPh(2))(mu-Cl)(diolefin)(eta(3)-C3H5)] (diolefin = COD (4), 2,5-norbornadiene (NBD) (5)), containing one chloride anion and one thiophosphinito group as bridging ligands, have been synthesised by redistribution reactions starting from the corresponding home-bridged compounds [Rh-2(mu-SPPh(2))(2)(diolefin)(2)], [Rh-2(mu-Cl)(2)(diolefin)(2)] or [Pd-2(mu-Cl)(2)(eta(3)-C3H5)(2)]. The structural X-ray analysis carried out for one member of this series, [Rh-2(mu-SPPh(2))(mu-Cl)(COD)(2)], has shown the bridging P,S-coordination of the thiophosphinito ligand. The intermetallic separation, 3.291(2) Angstrom, excludes any significant direct metal-metalinteraction.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 11/07/20 alle ore 18:17:40