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Titolo:
UNPRECEDENTED RING EXPANSION OF [60]FULLERENE - INCORPORATION OF NITROGEN AT AN OPEN 6,6-RING JUNCTURE BY REGIOSPECIFIC REDUCTION OF OXYCARBONYLAZIRIDINO-[2'3' 1,2][60]FULLERENES - SYNTHESIS OF 1A-AZA-1(6A)-HOMO[60]FULLERENE, C60H2NH/
Autore:
BANKS MR; CADOGAN JIG; GOSNEY I; HENDERSON AJ; HODGSON PKG; KERR WG; KERTH A; LANGRIDGESMITH PRR; MILLAR JRA; MOUNT AR; PARKINSON JA; TAYLOR AT; THORNBURN P;
Indirizzi:
UNIV EDINBURGH,DEPT CHEM,W MAINS RD EDINBURGH EH9 3JJ MIDLOTHIAN SCOTLAND UNIV LONDON IMPERIAL COLL SCI TECHNOL & MED,DEPT CHEM LONDON SW7 2AY ENGLAND BP INT LTD,RES & ENGN CTR SUNBURY TW16 7LN MIDDX ENGLAND
Titolo Testata:
Chemical communications
fascicolo: 4, , anno: 1996,
pagine: 507 - 508
SICI:
1359-7345(1996):4<507:UREO[->2.0.ZU;2-D
Fonte:
ISI
Lingua:
ENG
Soggetto:
C60;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
18
Recensione:
Indirizzi per estratti:
Citazione:
M.R. Banks et al., "UNPRECEDENTED RING EXPANSION OF [60]FULLERENE - INCORPORATION OF NITROGEN AT AN OPEN 6,6-RING JUNCTURE BY REGIOSPECIFIC REDUCTION OF OXYCARBONYLAZIRIDINO-[2'3' 1,2][60]FULLERENES - SYNTHESIS OF 1A-AZA-1(6A)-HOMO[60]FULLERENE, C60H2NH/", Chemical communications, (4), 1996, pp. 507-508

Abstract

Upon treatment with zinc in glacial acetic acid, N-oxycarbonylaziridino[2',3':1,2][60]fullerenes 3 undergo a reversible reductive cleavage of the bridgehead C-C bond to provide the first examples of bridged fulleroids 4 having an open 6,6-ring juncture; deprotection of the N-tert-butoxycarbonyI-derivative 4a allows the convenient synthesis of C60H2NH 5, the parent member of this new class of bridged fulleroids.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 11/07/20 alle ore 11:20:22