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Titolo:
CHEMICALLY OXIDATIVE SYNTHESIS AND HYDROLYSIS OF POLY[1-(2-CYANOETHYL)PYRROLE]
Autore:
YAMAUCHI T; KOJIMA K; TANAKA K; UNUMA T; SHIMOMURA M; MIYAUCHI S;
Indirizzi:
NAGAOKA UNIV TECHNOL,DEPT BIOENGN NAGAOKA NIIGATA 94021 JAPAN
Titolo Testata:
Polymer
fascicolo: 7, volume: 37, anno: 1996,
pagine: 1289 - 1291
SICI:
0032-3861(1996)37:7<1289:COSAHO>2.0.ZU;2-R
Fonte:
ISI
Lingua:
ENG
Soggetto:
GLUCOSE-OXIDASE; POLYPYRROLE; POLYMERIZATION; ELECTRODES; ENZYME;
Keywords:
POLY[1-(2-CYANOETHYL)PYRROLE]; HYDROLYSIS; CHEMICALLY OXIDATIVE POLYMERIZATION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
13
Recensione:
Indirizzi per estratti:
Citazione:
T. Yamauchi et al., "CHEMICALLY OXIDATIVE SYNTHESIS AND HYDROLYSIS OF POLY[1-(2-CYANOETHYL)PYRROLE]", Polymer, 37(7), 1996, pp. 1289-1291

Abstract

1-(2-Cyanoethyl)pyrrole was chemically polymerized in acetonitrile byusing iron(III) perchlorate as an oxidizing agent. Poly[1-(2-cyanoethyl)pyrrole] obtained as black powder was hydrolysed with potassium hydroxide to convert cyano groups of the polymer to carboxyl groups. The hydrolysis of the cyano groups was confirmed by means of i.r. spectroscopy. The electric conductivities of these polymers were investigated and it was shown that poly[1-(2-cyanoethyl)pyrrole] behaved as a conductive polymer while the hydrolysed polymer behaved as an insulator.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 28/09/20 alle ore 17:58:42