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Titolo:
SOLVENT EFFECTS ON MOLECULAR AND IONIC SPECTRA .7. MODELING THE ABSORPTION AND ELECTROABSORPTION SPECTRA OF PENTAAMMINE-RUTHENIUM(II) PYRAZINE AND ITS CONJUGATE ACID IN WATER
Autore:
ZENG J; HUSH NS; REIMERS JR;
Indirizzi:
UNIV SYDNEY,DEPT PHYS & THEORET CHEM SYDNEY NSW 2006 AUSTRALIA UNIV SYDNEY,DEPT PHYS & THEORET CHEM SYDNEY NSW 2006 AUSTRALIA UNIV SYDNEY,DEPT BIOCHEM SYDNEY NSW 2006 AUSTRALIA
Titolo Testata:
Journal of the American Chemical Society
fascicolo: 8, volume: 118, anno: 1996,
pagine: 2059 - 2068
SICI:
0002-7863(1996)118:8<2059:SEOMAI>2.0.ZU;2-E
Fonte:
ISI
Lingua:
ENG
Soggetto:
TRANSITION-METAL COMPLEXES; DIFFERENTIAL-OVERLAP TECHNIQUE; ENERGY PERTURBATION-METHODS; MONTE-CARLO CALCULATIONS; ELECTRON-TRANSFER; INTERMEDIATE NEGLECT; REACTION-FIELD; BIS(PENTAAMMINERUTHENIUM) COMPLEXES; REDOX THERMODYNAMICS; COMPUTER-SIMULATIONS;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
100
Recensione:
Indirizzi per estratti:
Citazione:
J. Zeng et al., "SOLVENT EFFECTS ON MOLECULAR AND IONIC SPECTRA .7. MODELING THE ABSORPTION AND ELECTROABSORPTION SPECTRA OF PENTAAMMINE-RUTHENIUM(II) PYRAZINE AND ITS CONJUGATE ACID IN WATER", Journal of the American Chemical Society, 118(8), 1996, pp. 2059-2068

Abstract

This work brings to a focus a series of papers concerning the modeling of solvent shifts in systems in which specific solute-solvent interactions such as hydrogen bonding occur: we consider the interpretation of the metal-to-ligand charge-transfer (MLCT) absorption and electroabsorption spectra of Ru2+(NH3)(5)-pyrazine and its conjugate acid Ru2+(NH3)(5)-pyrazine-H+ in dilute aqueous solution. The electroabsorption spectra of these complexes (among the first to be observed for inorganic complexes) taken in S. G. Boxer's laboratory indicated that very small dipole moment changes occur on excitation from the ground to the excited state; it has been found necessary to develop and extensively test, in earlier parts of this series, a sophisticated model for solvent-solute interactions in order to interpret these experimental results. In our approach, first, nb initio MCSCF and INDO methods are used toestimate the gas-phase electronic excitation energies; second, Monte Carlo simulations are performed to determine the ground-state liquid structures; finally, the solvent shifts and excited-state dipole moments are evaluated on the basis of the gas-phase charge distributions andthe explicit ground-state solvent structures. A variety of potential surfaces and boundary conditions are used in the simulations, and somevariation in the liquid structures but little variation in the calculated solvent shifts and dipole moment changes result. The calculated solution frequencies agree quite well with those observed, and the anomalously low values observed for dipole moment change are reproduced; the Magnuson and Taube model for the electronic structure of Ru2+(NH3)(5)-pyrazine-H+ is verified.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 02/12/20 alle ore 15:06:21