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Titolo:
BASE-CATALYZED ISOMERISM IN ELFAMYCIN ANTIBIOTICS - STRUCTURES OF GANEFROMYCIN-EPSILON AND GANEFROMYCIN-EPSILON(1)
Autore:
CARTER GT; TISCHLER M; WEST RR; BAILEY AE;
Indirizzi:
WYETH AYERST RES,LEDERLE LABS PEARL RIVER NY 10965
Titolo Testata:
Journal of antibiotics
fascicolo: 11, volume: 48, anno: 1995,
pagine: 1312 - 1319
SICI:
0021-8820(1995)48:11<1312:BIIEA->2.0.ZU;2-N
Fonte:
ISI
Lingua:
ENG
Soggetto:
LL-E19020-ALPHA; AURODOX; CHEMISTRY; COMPLEX;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
14
Recensione:
Indirizzi per estratti:
Citazione:
G.T. Carter et al., "BASE-CATALYZED ISOMERISM IN ELFAMYCIN ANTIBIOTICS - STRUCTURES OF GANEFROMYCIN-EPSILON AND GANEFROMYCIN-EPSILON(1)", Journal of antibiotics, 48(11), 1995, pp. 1312-1319

Abstract

The structures of ganefromycins epsilon (2a) and epsilon(1) (2b) havebeen determined by spectroscopic techniques. The compounds are isomeric deoxygenated precursors of the parent antibiotics ganefromycins alpha and beta. The nature of the isomerism was determined by chemical interconversion experiments and spectroscopic analysis to be a change inconfiguration at C-21. Evidence is provided for other cases of this type of isomerism in the elfamycin class of antibiotics.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 03/07/20 alle ore 23:01:29