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Titolo:
REGIOSPECIFIC AROMATIC CHLORINATION OF ALKYL PHENYL ETHERS USING SODIUM-CHLORITE CATALYZED BY MANGANESE(III) ACETYLACETONATE AND MOIST ALUMINA IN DICHLOROMETHANE
Autore:
HIRANO M; YAKABE S; MONOBE H; CLARK JH; MORIMOTO T;
Indirizzi:
TOKYO UNIV AGR & TECHNOL,FAC TECHNOL,DEPT APPL CHEM TOKYO 184 JAPAN UNIV YORK,DEPT CHEM YORK YO1 5DD N YORKSHIRE ENGLAND
Titolo Testata:
Journal of the Chemical Society. Perkin transactions. I
fascicolo: 20, , anno: 1997,
pagine: 3081 - 3085
SICI:
0300-922X(1997):20<3081:RACOAP>2.0.ZU;2-#
Fonte:
ISI
Lingua:
ENG
Soggetto:
REGIOSELECTIVE PARA CHLORINATION; SILICA-GEL; ACIDIC SOLUTION; SULFURYL CHLORIDE; N-CHLOROAMINES; ELECTROPHILIC CHLORINATION; UNFUNCTIONALIZED OLEFINS; ASYMMETRIC EPOXIDATION; AEROBIC EPOXIDATION; HALOGENATION;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Citazioni:
68
Recensione:
Indirizzi per estratti:
Citazione:
M. Hirano et al., "REGIOSPECIFIC AROMATIC CHLORINATION OF ALKYL PHENYL ETHERS USING SODIUM-CHLORITE CATALYZED BY MANGANESE(III) ACETYLACETONATE AND MOIST ALUMINA IN DICHLOROMETHANE", Journal of the Chemical Society. Perkin transactions. I, (20), 1997, pp. 3081-3085

Abstract

A solid-liquid biphasic system (dichloromethane and chromatographic neutral alumina) has been tested for the aromatic chlorination of various alkyl aryl ethers using a reagent combination of sodium chlorite and manganese(III) acetylacetonate catalyst. Efficient incorporation of a chlorine atom into the benzene ring with high para-selectivity results. This catalytic system is also applicable to the regiocontrolled chlorination of polyether substrates.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 19/09/20 alle ore 18:32:50