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Titolo:
COMPLEXES OF PERHALOGENATED CYCLOPENTADIENES AND ALKYNES .19. STUDIESON THE SYNTHESIS AND REACTIVITY OF CYMANTRENYLALKOXYSILANES [C5X5-N(SIME2OR)(N)]MN(CO)(3) (N = 1, 2, X = CL, BR, H)
Autore:
SUNKEL K; SCHUBERT S; HOFMANN J;
Indirizzi:
UNIV MUNICH,INST ANORGAN CHEM,MEISERSTR 1 D-80333 MUNICH GERMANY
Titolo Testata:
Journal of organometallic chemistry
fascicolo: 1-2, volume: 541, anno: 1997,
pagine: 199 - 206
SICI:
0022-328X(1997)541:1-2<199:COPCAA>2.0.ZU;2-R
Fonte:
ISI
Lingua:
GER
Soggetto:
COORDINATION CHEMISTRY; SILICON; MANGANESE; ALCOHOLS; DERIVATIVES; ALKOXYSILANES; HYDROSILANES; CONDENSATION; MECHANISM; BEHAVIOR;
Keywords:
MANGANESE; CYCLOPENTADIENYL; ALKOXYSILANE;
Tipo documento:
Article
Natura:
Periodico
Settore Disciplinare:
Science Citation Index Expanded
Science Citation Index Expanded
Citazioni:
39
Recensione:
Indirizzi per estratti:
Citazione:
K. Sunkel et al., "COMPLEXES OF PERHALOGENATED CYCLOPENTADIENES AND ALKYNES .19. STUDIESON THE SYNTHESIS AND REACTIVITY OF CYMANTRENYLALKOXYSILANES [C5X5-N(SIME2OR)(N)]MN(CO)(3) (N = 1, 2, X = CL, BR, H)", Journal of organometallic chemistry, 541(1-2), 1997, pp. 199-206

Abstract

Treatment of the cyclopentadienylsilanes [C5X4(SiMe2H)]Mn(CO)(3) (X=Br, Cl, H) and [C5Br3(SiMe2H)(2)]Mn(CO)(3) with PdCl2 yields the corresponding chlorosilanes 1a-c and 2. From these and alcohols CnH2n+1OH (n=1-10) the cymantrenyl-alkoxysilanes [C5X4(SiMe2OR)]Mn(CO)(3) 3-5 and [C5Br3(SiMe2OR)(2)]Mn(CO)(3) 6 can be obtained. (C) 1997 Elsevier Science S.A.

ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 09/08/20 alle ore 23:14:54