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Titolo: Metal-support interactions in cobalt-aluminum co-precipitated catalysts: XPS and CO adsorption studies
Autore: Khassin, AA; Yurieva, TM; Kaichev, VV; Bukhtiyarov, VI; Budneva, AA; Paukshtis, EA; Parmon, VN;
- Indirizzi:
- Boreskov Inst Ctalysis, Novosibirsk 630090, Russia Boreskov Inst CtalysisNovosibirsk Russia 630090 osibirsk 630090, Russia
- Titolo Testata:
- JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL
fascicolo: 1-2,
volume: 175,
anno: 2001,
pagine: 189 - 204
- SICI:
- 1381-1169(20011023)175:1-2<189:MIICCC>2.0.ZU;2-0
- Fonte:
- ISI
- Lingua:
- ENG
- Soggetto:
- FISCHER-TROPSCH CATALYSTS; X-RAY PHOTOELECTRON; CARBON-MONOXIDE; SURFACE-PROPERTIES; HYDROGEN; SILICA; TPR; REDUCIBILITY; SPECTROSCOPY; INTERFACE;
- Keywords:
- cobalt; alumina; XPS; carbon monoxide; metal-support interaction;
- Tipo documento:
- Article
- Natura:
- Periodico
- Settore Disciplinare:
- Physical, Chemical & Earth Sciences
- Citazioni:
- 41
- Recensione:
- Indirizzi per estratti:
- Indirizzo: Khassin, AA Boreskov Inst Ctalysis, 5,Pr Lavtentieva, Novosibirsk 630090, Russia Boreskov Inst Ctalysis 5,Pr Lavtentieva Novosibirsk Russia 630090
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- Citazione:
- A.A. Khassin et al., "Metal-support interactions in cobalt-aluminum co-precipitated catalysts: XPS and CO adsorption studies", J MOL CAT A, 175(1-2), 2001, pp. 189-204
Abstract
Cobalt-aluminum catalysts were prepared using either the precipitation of Co2+ in the presence of freshly prepared Zn-Al hydrotalcite (the promoted sample) or the co-precipitation of Co2+ and Al3+ (the unpromoted samples). The evolution of the initial hydrotalcite-like structure was monitored during its calcination and the reductive treatment by means of XPS. It was shownthat at 480 degreesC the reduction of the calcined samples results in the formation of Co-0 species, the further reduction at 650 degreesC results inan increase of the amount of the Coo species. The samples reduced at 650 degreesC chemisorb readily carbon monoxide at 77 K, while the sample reducedat 480 degreesC does not chemisorb CO at 77 K. At elevated temperatures, all reduced samples are found to be able to chemisorb Co-0. Terminal CO moieties as well as monodentate carbonates, formates and carboxyl species were detected at the surface of the reduced samples at their exposure to the CO medium at the elevated temperature. The intensity of the IR absorption bands of chemisorbed CO are found proportional to the surface fraction of the Co-0 species, measured by XPS. The apparent red shift of the IR absorption bands is observed for CO adsorbed on the samples reduced at 480 degreesC. The obtained data correlate with the catalytic properties of the Co-Al samples in hydrogenation reactions. The conclusion on the existence of a strong metal-support interaction in the samples under the study is made. (C) 2001 Elsevier Science B.V. All rights reserved.
ASDD Area Sistemi Dipartimentali e Documentali, Università di Bologna, Catalogo delle riviste ed altri periodici
Documento generato il 20/05/13 alle ore 19:58:57